The I3C shielding of the isotopomers CH,Cl, CH,DCl, CHD,Cl, and CD,C1 has been calculated for a range of temperatures from an self-consistent field (SCF) shielding surface computed by Buckingham and Olegario. It is found that each successive deuterium substitution increases the shielding by about 0.
Infrared photochemistry of (CH3)2Cl+, (CH3)Cl+ (CD3) and (CD3)2Cl+ in the gas phase using low-intensity cw laser radiation
โ Scribed by D.S. Bomse; J.L. Beauchamp
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 579 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The occurrence and magnitude of secondary kinetic isotope effects in the gas phase has been detcrmmcd for deuterium abstraction from the CD3 group in CD$ZH$l. CD$HDCI. and CD-&D&l by phorochemically generated \_eroundstaxe chlorine aloms. Over the temperature range lo-94ยฐC a discernible "inverse" ki
Rate constants for the reactions of OH radicals and Cl atoms with CH,CH,NO>, CH,CH,CH,NO,, CH3CH2CH2CHzN02, and CH,CH2CH2CH,CH2N02 have been determined at 295+3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis co
The kinetics of the gas-phase reactions of the OH radical with (C,H,O),PO and (CH30)2P(S)C1 and of the reactions of NO, radicals and O3 with (CH,O),P(S)Cl have been studied at room temperature. Using a relative rate technique, the rate constants determined for the reactions of the OH radical with (C