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The vibrational predissociation lifetime of the He…N+2 (X, ν = 1) complex

✍ Scribed by A.A. Buchachenko; A.Yu. Baisogolov; N.F. Stepanov

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
322 KB
Volume
220
Category
Article
ISSN
0009-2614

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✦ Synopsis

Approximate quantum calculations are performed on the energy levels and predissociation lifetime of the He...Nz (X 'El , v= 1) complex using four different analytical fits to the ab initio potential energy surface. The large discrepancies found in these quantities for potentials of similar origins reveal the crucial importance of the form and condition of the fitting procedure.

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