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The vibrational deactivation of 12C16O by H2 and D2 in liquid D2 solution

✍ Scribed by G.J. Wilson; M.L. Turnidge; C.J.S.M. Simpson

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 326 KB
Volume: 214
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(93)85638-5

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✦ Synopsis

Rate constants for the vibrational deactivation of 12C'60( u= 1) by Hz and D1 have been measured in liquid D2 solution over the temperature range 25 to 35 K. The '2C'60 was vibrationally excited using a frequency-doubled CO2 laser and the resulting infrared fluorescence was analysed to yield the rate constants. The rate constants for the CO-H2 system were found to tie slightly below the extrapolation of gas-phase data and to increase slightly with falling temperature, while those for CO-D, were significantly lower than in the gas phase and were invariant with temperature.

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