The results are especially encouraging in the light of Konowalov's calculation [8]. He found that Hulth&n functions (integral transforms of 1s functions), which are somewhat better than k,(q) in the Z-electron+atomic case, reduce to scaled 1s functions in H2, except for larger R values. Since k, (v)
Vibrational spectra and anharmonicity of H2O, D2O and HOD in dilute solutions
β Scribed by A. Burneau; J. Corset
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 484 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
B complexes (B stands for a base or anion) in binary or ternary solutions have been studied. betwesn 1000 and 11000 cm-l. Calculation shows that the anharmonic constants depend ou the symmetry of the interaction: for H20 and D20, 92 decreases and 31 sad 39 increase indicating decoupling of the vibrators. A new interpretation of the experimental results of Greinacber. Liittke sad Mecke (1955) is
given.
π SIMILAR VOLUMES
Fundamental frcquencres for Hz0 Isolated m D,O Ice I, have been determmed by a combmation of Founer transform infrared difference spectroscopy and Interference enhanced Raman spectroscopy. The results are mterpreted m terms of a ~2 frequency (1732 cm-') such that rermt resonance of vt wrth 2~2 cause
SRS of the valence band ofliquid Hz0 and I&O are obkked using a ti&'ttosecond pdlsc From a @mitched ruby laser. ke SRS contours obtained .are in ovextLI rgreement with &ose of earlier workers us@ picosecond pulses %ad hefp cL~ify the results of one of the p&lished works. The bmad SRS bnnds arc less