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The unique chemistry of platina-β-diketones

✍ Scribed by Steinborn, Dirk

Book ID: 121456571
Publisher: Royal Society of Chemistry
Year: 2005
Tongue: English
Weight: 306 KB
Volume: 16
Category: Article
ISSN: 1477-9226
DOI: 10.1039/B506277M

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The platina-b-diketones [Pt 2 {(COR) 2 H} 2 (l-Cl) 2 ] (1, R = Me a, Et b) react with phosphines L in a molar ratio of 1 : 4 through cleavage of acetaldehyde to give acylplatinum(II) complexes trans-[Pt(COR)Cl(L) 2 ] (2) (R/L = Me/P(p-FC 6 H 4 ) 3 a, Me/P(p-CH 2 =CHC 6 H 4 )Ph 2 b, Me/P(n-Bu) 3 c, E