The Unique Chemistry of Platina-β-diketones
✍ Scribed by Dirk Steinborn
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 8 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The platina-b-diketones [Pt 2 {(COR) 2 H} 2 (l-Cl) 2 ] (1, R = Me a, Et b) react with phosphines L in a molar ratio of 1 : 4 through cleavage of acetaldehyde to give acylplatinum(II) complexes trans-[Pt(COR)Cl(L) 2 ] (2) (R/L = Me/P(p-FC 6 H 4 ) 3 a, Me/P(p-CH 2 =CHC 6 H 4 )Ph 2 b, Me/P(n-Bu) 3 c, E
Thin films of scandium oxide, Sc 2 O 3 , have been deposited by liquid-injection MOCVD using tetrahydrofuran solutions of the novel precursors Sc(tmod) 3 (tmod = 2,2,7-trimethyloctane-3,5-dionate) and Sc(mhd) 3 (mhd = 6-methylheptane-2,4-dionate). The properties of the films are compared to those of
The reactions of Phenyliodonium dimedonate,l,with various double bonds were investigated.The products are always heterocyclic copmounds(5-member ring) in good yield. Until today,chemical studies on I-ylide 1 have been limited to its reactivity toward highly electrophilic agents3 and thermal decompos