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Anionic Tetranuclear Platina-β-diketonates of Platina-β-diketones – Organometallic Analogues of Platinum Blue Complexes

✍ Scribed by Michael Gerisch; Clemens Bruhn; Andrea Porzel; Dirk Steinborn

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
263 KB
Volume
1998
Category
Article
ISSN
1434-1948

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The platina-b-diketones [Pt 2 {(COR) 2 H} 2 (l-Cl) 2 ] (1, R = Me a, Et b) react with phosphines L in a molar ratio of 1 : 4 through cleavage of acetaldehyde to give acylplatinum(II) complexes trans-[Pt(COR)Cl(L) 2 ] (2) (R/L = Me/P(p-FC 6 H 4 ) 3 a, Me/P(p-CH 2 =CHC 6 H 4 )Ph 2 b, Me/P(n-Bu) 3 c, E