𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Reactivity of Dinuclear Platina-β-diketones toward Phosphines and Pyridines: Formation of Mononuclear Platina-β-diketones and Acyl(chloro)platinum(II) Complexes †

✍ Scribed by Gerisch, Michael; Heinemann, Frank W.; Bruhn, Clemens; Scholz, Joachim; Steinborn, Dirk

Book ID
125951740
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
276 KB
Volume
18
Category
Article
ISSN
0276-7333

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

On the Reactivity of Platina-β-diketones
On the Reactivity of Platina-β-diketones – Synthesis and Characterization of Acylplatinum(II) Complexes
✍ Dirk Steinborn; Tobias Hoffmann; Michael Gerisch; Clemens Bruhn; Harry Schmidt; 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 139 KB 👁 1 views

The platina-b-diketones [Pt 2 {(COR) 2 H} 2 (l-Cl) 2 ] (1, R = Me a, Et b) react with phosphines L in a molar ratio of 1 : 4 through cleavage of acetaldehyde to give acylplatinum(II) complexes trans-[Pt(COR)Cl(L) 2 ] (2) (R/L = Me/P(p-FC 6 H 4 ) 3 a, Me/P(p-CH 2 =CHC 6 H 4 )Ph 2 b, Me/P(n-Bu) 3 c, E