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The uncatalyzed gas phase hydrochlorination of alkenes I. Propene and isobutylene

✍ Scribed by Francois Amar; D.R. Dalton; Glenn Eisman; Michael J. Haugh


Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
219 KB
Volume
15
Category
Article
ISSN
0040-4039

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✦ Synopsis


In 1925 it was reported that after 400 days at one atmosphere total pressure, no gas phase reaction between propene and hydrogen chloride could be detected.1


πŸ“œ SIMILAR VOLUMES


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The gas phase reaction between allene and hydrogen chloride at pressures of one to ten atmospheres at 25\*ZΒ°C and 100\*2Β°C has been monitored in sealed glass and quartz vessels by proton magnetic resonance spectroscopy. The reaction is very slow. The products formed are 2-chloropropene Q), 2,2\_dic

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The reactions of ozone with propene and isobutene have been studied in the gas phase at 298'K and 530 Pa (4 torr) using a stopped-flow reactor coupled to a photoionization mass spectrometer. Reactant and product concentrations were followed as a function of reaction time. The major reaction products

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The rate law -d[O,]/dt = kl[A][OJ + k3[A][03]2/(k4 + kb[02]) has been found to obrain for the reaction of ozone with allene and with 1,2-butadiene. We now find that this rate law also applies to the reaction of ozone with ethylene and presumably with all lower alkenes. This generalizes the inhibiti

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## OMS Letters Dear Sir, ## Gas-phase Reactions of the Sulphur Distonic Ion (CH,),SCH,' with Alkenes Distonic ions are well recognized as key intermediates in the unimolecular reactions of radical cations in the gas phase'-, and the bimolecular chemistry of these species has been described in a

Kinetics of the addition of propene to c
✍ G. Debande; G. Huybrechts πŸ“‚ Article πŸ“… 1974 πŸ› John Wiley and Sons 🌐 English βš– 310 KB πŸ‘ 1 views

## Abstract The addition of propene to cyclohexa‐1,3‐diene has been studied between 512 and 638Β°K at pressures between 70 and 640 torr. The products are endo‐ and exo‐5‐methylbicyclo [2.2.2] oct‐2‐ene, and their formations are second order. The rate constants (in 1./mole‐sec) are given by The resu