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The uncatalyzed gas phase hydrochlorination of alkenes II. Allene

✍ Scribed by Francois Amar; D.R. Dalton; Glenn Eisman; Michael J. Haugh

Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
231 KB
Volume
15
Category
Article
ISSN
0040-4039

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✦ Synopsis

The gas phase reaction between allene and hydrogen chloride at pressures of one to ten atmospheres at 25*ZΒ°C and 100*2Β°C has been monitored in sealed glass and quartz vessels by proton magnetic resonance spectroscopy.

The reaction is very slow. The products formed are 2-chloropropene Q), 2,2_dichloropropane

(2) and methyl acetylene Q); exactly those

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The rate law -d[O,]/dt = kl[A][OJ + k3[A][03]2/(k4 + kb[02]) has been found to obrain for the reaction of ozone with allene and with 1,2-butadiene. We now find that this rate law also applies to the reaction of ozone with ethylene and presumably with all lower alkenes. This generalizes the inhibiti