## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
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Mechanism of the catalytic action of the mechanoactivated salt K2PTCL4in the gas-phase hydrochlorination of acetylene
โ Scribed by R. S. Mitchenko; A. A. Shubin; T. V. Krasnyakova
- Publisher
- Springer
- Year
- 2006
- Tongue
- English
- Weight
- 121 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0040-5760
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The gas phase reaction between allene and hydrogen chloride at pressures of one to ten atmospheres at 25\*ZยฐC and 100\*2ยฐC has been monitored in sealed glass and quartz vessels by proton magnetic resonance spectroscopy. The reaction is very slow. The products formed are 2-chloropropene Q), 2,2\_dic
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In 1925 it was reported that after 400 days at one atmosphere total pressure, no gas phase reaction between propene and hydrogen chloride could be detected.1