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Kinetics of the addition of propene to cyclohexa-1,3-diene in the gas phase

✍ Scribed by G. Debande; G. Huybrechts

Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
310 KB
Volume
6
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The addition of propene to cyclohexa‐1,3‐diene has been studied between 512 and 638°K at pressures between 70 and 640 torr. The products are endo‐ and exo‐5‐methylbicyclo [2.2.2] oct‐2‐ene, and their formations are second order. The rate constants (in 1./mole‐sec) are given by

The results are discussed in terms of a biradical mechanism.

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