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A biradical calculation model for the thermal dimerization of cyclohexa-1,3-diene in the gas phase

✍ Scribed by G. Huybrechts; B. Van Mele

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
131 KB
Volume
17
Category
Article
ISSN
0538-8066

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✦ Synopsis

De Mare et al. [13 studied the thermal Diels-Alder dimerization of cyclohexa-1,3-diene (CHD) to endo-dicyclohexadiene and exo-dicyclohexadiene (N and X, respectively) in a static Pyrex system. The temperature ranged from 471 to 639 K and the pressure was varied from 25 tp 630 torr. The formations of N and X are second order and 67, 1397 (1971).

259 (1982)

Kinet., 12, 253 (1980).

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