In the reaction of a-aminoacids with excess NaNO pyridine, stereospecific substitution(i.e. 2 in polyhydrogen fluorideretention of configuration) is observed with C6HllCH2CHNH2COOH, while a stereospecific rearrangment occurs in the case of phenylalanine.
The transformation of α-aminoacids into fluoroacids
✍ Scribed by Jill Barker; Rolf Keck; János Rétey
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 206 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The reactions of some a-aminoacids with excess sodium nitrite in polyhydrogen fluoride-pyridine are described.
The report by Faustini et al.' concerning the reaction of a-aminoacids with sodium nitrite in polyhydrogen fluoride-pyridine prompts us to communicate our own findings. In a previous communication from these laboratories2 it was re-
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