The reactions of some a-aminoacids with excess sodium nitrite in polyhydrogen fluoride-pyridine are described. The report by Faustini et al.' concerning the reaction of a-aminoacids with sodium nitrite in polyhydrogen fluoride-pyridine prompts us to communicate our own findings. In a previous commu
Stereospecificity in the transformation of α-aminoacids into fluoroacids
✍ Scribed by Franco Faustini; Sergio De Munari; Achille Panzeri; Vittoria Villa; Carmelo A. Gandolfi
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 183 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
In the reaction of a-aminoacids with excess NaNO pyridine, stereospecific substitution(i.e.
2 in polyhydrogen fluorideretention of configuration) is observed with C6HllCH2CHNH2COOH, while a stereospecific rearrangment occurs in the case of phenylalanine.
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