The Lewis acid-promoted reaction of 3,3-disul3stituted allyltins toward aldehydes was found to be stefeospecific; the (E)-reagent gave syn-products and the (Z)-one gave anti-products. This is in contrast to that of 3-mono-su~tituted congeners which are known to react syn-stereoselectively regardless
Stereospecificity in the Silicon Tethered α-(Methyl)allylation of Aldehydes.
✍ Scribed by Jeremy Roberts; Michael J. Hall; Stuart P. Green
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 175 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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