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A general and accurate nmr determination of the enantiomeric purity of α-aminoacids and α-aminoacid derivatives

✍ Scribed by Monique Calmes; Jacques Daunis; Robert Jacquier; Jean Verducci

Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 589 KB
Volume: 43
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)86812-5

No coin nor oath required. For personal study only.

✦ Synopsis

Derivatfzatfon of oxmfnoacids. a-aminoesters and *amlnolactones as N-acetyl dertvatfves allow the accurate t?HR determination of the enantfomerfc purity. In these conditions the major coordfnatfon site with a chlral shfjt reagent will correspond to the Nm observation sfte. Ezperfmentat factors teadfng to the highest M6 values are ascertatned. No ztratghtforward correlation wtth absolute conftguratlons can be establtshed.

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