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The Thermodynamics of Polyamide−DNA Recognition: Hairpin Polyamide Binding in the Minor Groove of Duplex DNA †

✍ Scribed by Pilch, Daniel S.; Poklar, Nataša; Baird, Eldon E.; Dervan, Peter B.; Breslauer, Kenneth J.

Book ID
126946763
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
116 KB
Volume
38
Category
Article
ISSN
0006-2960

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✍ Victor C. Rucker; Christian Melander; Peter B. Dervan 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 German ⚖ 398 KB

## Abstract Antiparallel polyamides containing 1__H__‐pyrrole, 1__H__‐imidazole, and 3‐hydroxy‐1__H__‐pyrrole amino acids display a preference for minor‐groove binding oriented NC with respect to the 5′‐3′ direction of the DNA helix. We find that replacement of a central Py/Py pair with a __β__/__