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NMR Characterization of Hairpin Polyamide Complexes with the Minor Groove of DNA

✍ Scribed by de Clairac, Rafael Peláez Lamamie; Geierstanger, Bernhard H.; Mrksich, Milan; Dervan, Peter B.; Wemmer, David E.

Book ID
120573939
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
290 KB
Volume
119
Category
Article
ISSN
0002-7863

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Influence of β-Alanine on Hairpin Polyam
Influence of β-Alanine on Hairpin Polyamide Orientation in the DNA Minor Groove
✍ Victor C. Rucker; Christian Melander; Peter B. Dervan 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 German ⚖ 398 KB

## Abstract Antiparallel polyamides containing 1__H__‐pyrrole, 1__H__‐imidazole, and 3‐hydroxy‐1__H__‐pyrrole amino acids display a preference for minor‐groove binding oriented NC with respect to the 5′‐3′ direction of the DNA helix. We find that replacement of a central Py/Py pair with a __β__/__