The Thermochemistry of the Gas Phase Equilibrium I 2 + CH 4 [UNK] CH 3 I + HI and the Heat of Formation of the Methyl Radical 1
β Scribed by Golden, David M.; Walsh, Robin; Benson, Sidney W.
- Book ID
- 121440981
- Publisher
- American Chemical Society
- Year
- 1965
- Tongue
- English
- Weight
- 649 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The rate of the reaction CH212 + H I 2 CH,I + I , has been followed spectrophotometrically from 201 .O to 31 1 .Z0. The rate constant for the reaction I + CH,I, CH,I + I, fits the equation, log (k,/M-'sec-') = 11.45 f 0.18 -(15.11 f 0.44)/0. This value, combined with the assumption that E2 = 0 & 1 k
The kinetics of the gas-phase reaction of CH3F with 12 have been studied spectrophotometrically from 629 to 710 K, and were determined to be consistent with the following mechanism: (KIJ squares analysis of the kinetic data taken in the initial stages of reaction resulted in log k4 (M-w) = (11.3 f