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The thermochemistry of the gas phase reaction: CF3CH2Br+I2=CF3CH2I+IBr. Polarity effects in thermochemistry

โœ Scribed by Gary S. Buckley; W.G.F. Ford; Alan S. Rodgers


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
527 KB
Volume
42
Category
Article
ISSN
0040-6031

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๐Ÿ“œ SIMILAR VOLUMES


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The kinetics and equilibrium of the gas-phase reaction of CHaCFZBr with IZ were studied spectrophotometrically from 581 to 662ยฐK and determined to be consistent with the following mechanism: KIZ

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Disproportionation/combination rate constant ratios, k , / k , , have been measured for the collision between CF3CH2CH2 and CF3 radicals to be 0.022 ? 0 002 and for CF3CH2CH2 and CF3CH2CH2 radicals to be 0.100 IT 0.002. Comparison to previous work from this laboratory for the reaction of CF3CH2CHCI

Substituent effects on the disproportion
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Rate constant ratios, k d /k c , for the disproportionation/combination reaction at a temperature of 295 ฯฎ 2 K, have been measured as 0.034 ฯฎ 0.009 for the collision between CF 3 CH 2 CF 2 ฯฉ CF 3 radicals and as 0.075 ฯฎ 0.019 for CF 3 CH 2 CF 2 ฯฉ CF 3 CH 2 CF 2 radicals. The effect of the two fluori

A kinetic study of the reaction of fluor
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A variety of relative and absolute techniques have been used to measure the reactivity of fluorine atoms with a series of halogenated organic compounds and CO. The following rate constants were derived, in units of cm3 molecule-' s-l: CH3F, (3.7 2 0.8) X CH3C1, (3.3 2 0.71 X 10 -'I; CH3Br, (3.0 2 0.

Substituent effects on the disproportion
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Disproportionationkombination rate constant ratios, kd/&[, for the reactive collision between CF3CH2CHX + CF, radicals and between CF3CH2CHX + CF3CH2CHX radicals have been measured for X = CF, The kd/k, = 0.066 -t 0 01 3 when H is transferred to the CF3 radical and 0 I25 ? 0.025 for H transfer to th