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✦   LIBER   ✦

The kinetics and equilibrium of the gas-phase reaction CH3CF2Br + I2 = CH3CF2I + IBr the C-Br bond dissociation energy in 1,1-difluorobromoethane

✍ Scribed by J. M. Pickard; A. S. Rodgers

Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
388 KB
Volume
9
Category
Article
ISSN
0538-8066

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✦ Synopsis

The kinetics and equilibrium of the gas-phase reaction of CHaCFZBr with IZ were studied spectrophotometrically from 581 to 662Β°K and determined to be consistent with the following mechanism: KIZ

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## Abstract The kinetics of gas‐phase reaction of CH~3~CF~2~I with HI were studied from 496 to 549K and have been shown to be consistent with the following mechanism: equation image A least squares treatment of the data gave where ΞΈ = 2.303 __RT__ kcal/mole. The observed activation energy __E__