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Gas-Phase Collisional Relaxation of the CH 2 I Radical after UV Photolysis of CH 2 I 2

✍ Scribed by Lenzer, Thomas; Oum, Kawon; Schroeder, Jörg; Sekiguchi, Kentaro

Book ID
127333245
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
151 KB
Volume
109
Category
Article
ISSN
1089-5639

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The rate of the reaction CH212 + H I 2 CH,I + I , has been followed spectrophotometrically from 201 .O to 31 1 .Z0. The rate constant for the reaction I + CH,I, CH,I + I, fits the equation, log (k,/M-'sec-') = 11.45 f 0.18 -(15.11 f 0.44)/0. This value, combined with the assumption that E2 = 0 & 1 k