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Spectroscopic Study of the I 2 Formation from the Photolysis of Iodomethanes (CHI 3 , CH 2 I 2 , CH 3 I, and CH 2 ICl) at Different Wavelengths

✍ Scribed by Tu, Cian-Ping; Cheng, Hsin-I; Chang, Bor-Chen


Book ID
126972251
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
1007 KB
Volume
117
Category
Article
ISSN
1089-5639

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Kinetic studies of the reactions CH2I2 +
✍ Shozo Furuyama; David M. Golden; Sidney W. Benson πŸ“‚ Article πŸ“… 1969 πŸ› John Wiley and Sons 🌐 English βš– 489 KB πŸ‘ 1 views

The rate of the reaction CH212 + H I 2 CH,I + I , has been followed spectrophotometrically from 201 .O to 31 1 .Z0. The rate constant for the reaction I + CH,I, CH,I + I, fits the equation, log (k,/M-'sec-') = 11.45 f 0.18 -(15.11 f 0.44)/0. This value, combined with the assumption that E2 = 0 & 1 k