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THE KINETICS, STATICS AND ENERGETICS OF THE THERMAL REACTION CH 2 I-CH 2 I = CH 2 =CH 2 + I 2 IN CARBON TETRACHLORIDE SOLUTIONS

✍ Scribed by Polissar, Milton J.

Book ID
127097255
Publisher
American Chemical Society
Year
1930
Tongue
English
Weight
804 KB
Volume
52
Category
Article
ISSN
0002-7863

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Kinetic studies of the reactions CH2I2 + HI⇄CH3I + I2 and 2 CH3I⇄CH4 + CH2I2 the heat of formation of the iodomethyl radical
✍ Shozo Furuyama; David M. Golden; Sidney W. Benson πŸ“‚ Article πŸ“… 1969 πŸ› John Wiley and Sons 🌐 English βš– 489 KB πŸ‘ 1 views

The rate of the reaction CH212 + H I 2 CH,I + I , has been followed spectrophotometrically from 201 .O to 31 1 .Z0. The rate constant for the reaction I + CH,I, CH,I + I, fits the equation, log (k,/M-'sec-') = 11.45 f 0.18 -(15.11 f 0.44)/0. This value, combined with the assumption that E2 = 0 & 1 k