The thermal addition of trifluoromethylhypofluorite, CF3OF, to trichloroethene
โ Scribed by Hector Di Loreto; Joanna Czarnowski
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 347 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0022-1139
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The thermal gas-phase reaction of CF,OF with CCI,CC12 h a s been studied between 313.8 a n d 343 8 K The initial pressure of CF,OF was varied between 10.8 a n d 77.5 torr a n d that of CCI;,CCI, between 3.7 a n d 26 8 torr. CF,OF was always present in excess, varying t h e initial ratio of CF,OF t o
The kinetics of the thermal reaction between SF, and CF,OF has been studied between 142ยฐC and 185ยฐC. The reaction was found to be homogeneous and the only products formed are equimolecular amounts of SF, and CF,O,CF, and smaller amounts of CF,OSF,. The reaction mechanism was not affected by the tot
The kinetics of the thermal reaction between CF,OF and C,F, have been investigated between 20 and 75ยฐC. It is a homogeneous chain reaction of moderate length where the main product is a mixture of the two isomers l-C,F,OCF, (68%) and 2-C3F,0CF3 (32%). Equimolecular amounts of CF,OOCF, and CsF,, are