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The thermal addition of trifluoromethyl hypofluorite, CF3OF, to tetrachloroethene

✍ Scribed by Hector Di Loreto; Joanna Czarnowski


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
182 KB
Volume
74
Category
Article
ISSN
0022-1139

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πŸ“œ SIMILAR VOLUMES


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✍ J. Czarnowski πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 368 KB πŸ‘ 2 views

The thermal gas-phase reaction of CF,OF with CCI,CC12 h a s been studied between 313.8 a n d 343 8 K The initial pressure of CF,OF was varied between 10.8 a n d 77.5 torr a n d that of CCI;,CCI, between 3.7 a n d 26 8 torr. CF,OF was always present in excess, varying t h e initial ratio of CF,OF t o

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The oxidation of perfluorobutene-2 (C 4 F 8 ) initiated by trifluoromethyl hypofluorite (CF 3 OF) in presence of O 2 has been studied at 323.1, 332.6, 342.5, and 352.0 K, using a conventional static system. The initial pressure of CF 3 OF was varied between 4.8 and 23.6 Torr, that of C 4 F 8 between

Kinetics of the thermal decomposition of
✍ Maximiliano A. Burgos Paci; Gustavo A. ArgΓΌello; PlΓ‘cido GarcΓ­a; Helge Willner πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 84 KB

## Abstract Thermal decomposition of bis(trifluoromethyl) peroxydicarbonate has been studied. The mechanism of decomposition is a simple bond fission, homogeneous first‐order process when the reaction is carried out in the presence of inert gases such as N~2~ or CO. An activation energy of 28.5 kca

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The thermal addition of CF,0sCF3(T 1 to CF2CCl2(E) has been investigated between 49.6 and 69.5"C. The initial pressure of CFJ03CF3 was varied between 7 and 240 torr and that of CF2CC12 between 4 and 600 torr. Four products of formula CF30(E),00CF3, wherej = 1 + 4 are formed. The sum of the products