The thermal addition of trifluoromethyl hypofluorite, CF3OF, to tetrachloroethene
β Scribed by Hector Di Loreto; Joanna Czarnowski
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 182 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0022-1139
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π SIMILAR VOLUMES
The thermal gas-phase reaction of CF,OF with CCI,CC12 h a s been studied between 313.8 a n d 343 8 K The initial pressure of CF,OF was varied between 10.8 a n d 77.5 torr a n d that of CCI;,CCI, between 3.7 a n d 26 8 torr. CF,OF was always present in excess, varying t h e initial ratio of CF,OF t o
The oxidation of perfluorobutene-2 (C 4 F 8 ) initiated by trifluoromethyl hypofluorite (CF 3 OF) in presence of O 2 has been studied at 323.1, 332.6, 342.5, and 352.0 K, using a conventional static system. The initial pressure of CF 3 OF was varied between 4.8 and 23.6 Torr, that of C 4 F 8 between
## Abstract Thermal decomposition of bis(trifluoromethyl) peroxydicarbonate has been studied. The mechanism of decomposition is a simple bond fission, homogeneous firstβorder process when the reaction is carried out in the presence of inert gases such as N~2~ or CO. An activation energy of 28.5 kca
The thermal addition of CF,0sCF3(T 1 to CF2CCl2(E) has been investigated between 49.6 and 69.5"C. The initial pressure of CFJ03CF3 was varied between 7 and 240 torr and that of CF2CC12 between 4 and 600 torr. Four products of formula CF30(E),00CF3, wherej = 1 + 4 are formed. The sum of the products