The addition of trifluoromethylhypofluorite to hexafluoropropene dimers
โ Scribed by Carlo Corvaja; Francesca Cremonese; Walter Navarrini; Claudio Tonelli; Vito Tortelli
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 181 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
The kinetics of the thermal reaction between CF,OF and C,F, have been investigated between 20 and 75ยฐC. It is a homogeneous chain reaction of moderate length where the main product is a mixture of the two isomers l-C,F,OCF, (68%) and 2-C3F,0CF3 (32%). Equimolecular amounts of CF,OOCF, and CsF,, are
The reversible thermal gas-phase dimerization of hexafluoropropene to the four isomeric cyclobutanes has been studied by pressure change and by gasliquid chromatographic analysis in the temperature range of 645-708 K with initial pressures of olefin from 802 to 4820 mm Hg. The reaction was accuratel
Free radicals derived from some alkyl substituted cyclohexanol derivatives react with hexafluoropropene to give a variety of polyfluoroalkylated adducts. Stereochemistry of the processes is discussed and remote functionalisation of the methyl group in Chemie freier Radikale. 13. Addition von Alkylcy