✦ LIBER ✦

Free Radical Chemistry. 13 [1] Addition of Alkyl-Cyclohexanol Derivatives to Hexafluoropropene

✍ Scribed by Richard D. Chambers; Christopher Farren; Graham Sandford; Dmitri S. Yufit; Judith A. K. Howard

Publisher: John Wiley and Sons
Year: 2002
Tongue: German
Weight: 103 KB
Volume: 628
Category: Article
ISSN: 0372-7874
DOI: 10.1002/1521-3749(200208)628:8<1857::aid-zaac1857>3.0.co;2-z

No coin nor oath required. For personal study only.

✦ Synopsis

Free radicals derived from some alkyl substituted cyclohexanol derivatives react with hexafluoropropene to give a variety of polyfluoroalkylated adducts. Stereochemistry of the processes is discussed and remote functionalisation of the methyl group in Chemie freier Radikale. 13. Addition von Alkylcyclohexanol-Derivaten an Hexafluoropropen Inhaltsübersicht. Freie Radikale, die sich von einigen alkylsubstituierten Cyclohexanol-Derivaten ableiten, reagieren mit Hexafluoropropen unter Bildung einer Reihe von polyfluoroalkylierter Addukte. Die Stereochemie dieser Prozesse wird diskutiert und

📜 SIMILAR VOLUMES

ChemInform Abstract: Free Radical Chemis

ChemInform Abstract: Free Radical Chemistry. Part 10. Addition of Acyclic and Cyclic Alkanes to Hexafluoropropene.

✍ Richard D. Chambers; Robert W. Fuss; Robert C. H. Spink; Martin P. Greenhall; Al 📂 Article 📅 2000 🏛 John Wiley and Sons ⚖ 35 KB 👁 2 views

ChemInform Abstract: Free Radical Chemis

ChemInform Abstract: Free Radical Chemistry. Part 11. Additions of Cyclic and Acyclic Alcohols and Diols to Hexafluoropropene.

✍ Richard D. Chambers; Patrick Diter; Stephen N. Dunn; Christopher Farren; Graham 📂 Article 📅 2000 🏛 John Wiley and Sons ⚖ 32 KB 👁 2 views

ChemInform Abstract: Tin-Free Radical Ch

ChemInform Abstract: Tin-Free Radical Chemistry: Intramolecular Addition of Alkyl Radicals to Aldehydes and Ketones.

✍ Priscille Devin; Louis Fensterbank; Max Malacria 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 2 views

Free Radical Addition of Cyclopentane an

Free Radical Addition of Cyclopentane and Cyclohexane to Halogeno Derivatives of 1,1-Difluoroethene.

✍ Julian A. Cooper; Elodie Copin; Graham Sandford 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB

ChemInform Abstract: Radical Additions t

ChemInform Abstract: Radical Additions to Fluoroolefins. Photochemical Fluoroalkylation of Alkanols and Alkanediols with Perfluorovinyl Ethers; Photo-Supported O- Alkylation of Butane-1,4-diol with Hexafluoropropene.

✍ V. CIRKVA; R. POLAK; O. PALETA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB 👁 1 views

β-Alkyl and β-Alkyl-α-Hydroxy Carboxylic

β-Alkyl and β-Alkyl-α-Hydroxy Carboxylic Acid Derivatives from Radical or Ionic 1,4 Addition of Dialkylaluminum Chlorides to α,β-Unsaturated N-Acyl Urethanes

✍ Dipl.-Chem. Karola Rück; Prof. Dr. Horst Kunz 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 351 KB 👁 1 views

and treated with lBuCl (1.18 g, 12.8 mmol) directly after filtration. The mixture was stirred at room temperature for 12 h before the orange solution was evaporated to dryness. Recrystallization of the residue from toluene (ca. 30 mL) affords a yellow crystalline powder (2.50 g, 40%). which decompos