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The synthesis of asimilobin and the correction of its tetrahydrofuran segment's configuration

✍ Scribed by Zhi-Min Wang; Shi-Kai Tian; Min Shi

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 201 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)02577-5

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✦ Synopsis

A highly efficient synthetic method for the trans/threo/transbis-tetrahydrofuran (TI-IF) ring building block was established. The title compound was synthesized in thirteen steps from trans-l,4-dichloro-2-butene via a convergent route with a Wittig reaction as the key step. The absolute configuration of the THF segment of naturally occurring asimiiobin should be corrected.

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