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The first total synthesis of putaminoxin and determination of its absolute configuration

✍ Scribed by Gowravaram Sabitha; K. Yadagiri; R. Swapna; J.S. Yadav

Publisher: Elsevier Science
Year: 2009
Tongue: French
Weight: 238 KB
Volume: 50
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2009.07.055

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✦ Synopsis

Asymmetric synthesis of putaminoxin, a phytotoxic macrolide from the cultured dinoflagellate Amphidinium sp., has been accomplished. Absolute configuration of putaminoxin was concluded to be 1 from comparison of the NMR data and [a] D values of synthetic and natural putaminoxin.

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