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ChemInform Abstract: The Synthesis of Asimilobin and the Correction of Its Tetrahydrofuran Segment′s Configuration.

✍ Scribed by Zhi-Min Wang; Shi-Kai Tian; Min Shi

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
30
Category
Article
ISSN
0931-7597

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The synthesis of asimilobin and the corr
The synthesis of asimilobin and the correction of its tetrahydrofuran segment's configuration
✍ Zhi-Min Wang; Shi-Kai Tian; Min Shi 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 201 KB

A highly efficient synthetic method for the trans/threo/transbis-tetrahydrofuran (TI-IF) ring building block was established. The title compound was synthesized in thirteen steps from trans-l,4-dichloro-2-butene via a convergent route with a Wittig reaction as the key step. The absolute configuratio