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The synthesis of 5,6-Dihydro-1,4-oxathiin-2,3-dicarboxylic acid and some derivatives

✍ Scribed by P. Ten Haken


Book ID
112122293
Publisher
Journal of Heterocyclic Chemistry
Year
1970
Tongue
English
Weight
232 KB
Volume
7
Category
Article
ISSN
0022-152X

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Electron impact induced fragmentation of
✍ Vesa Nevalainen; Pirjo Vainiotalo πŸ“‚ Article πŸ“… 1986 πŸ› John Wiley and Sons 🌐 English βš– 709 KB

In the electron impact induced fragmentation of 2,3-disubstituted 5,6-dihydro-1,4-oxathiines, the cleavage of the heterocyclic ring proceeds through the retro Diels-Alder type of reaction. The further fragmentation of the resulting radical cation gives rise to substituted carbonyl or thiocarbonyl ca