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ChemInform Abstract: Reaction of Dichlorocarbene with 2,3-Dihydro-5,6-dimethyl-1,4-oxathiin and 2,3-Dihydro-5,6-dimethyl-1,4-dithiin.

✍ Scribed by A. D. BREWER; A. A. ZNOTINS


Book ID
112034906
Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
27
Category
Article
ISSN
0931-7597

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Electron impact induced fragmentation of
✍ Vesa Nevalainen; Pirjo Vainiotalo πŸ“‚ Article πŸ“… 1986 πŸ› John Wiley and Sons 🌐 English βš– 709 KB

In the electron impact induced fragmentation of 2,3-disubstituted 5,6-dihydro-1,4-oxathiines, the cleavage of the heterocyclic ring proceeds through the retro Diels-Alder type of reaction. The further fragmentation of the resulting radical cation gives rise to substituted carbonyl or thiocarbonyl ca