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Reaction of dichlorocarbene with 2,3-dihydro-5,6-dimethyl-1,4-oxathiin and 2,3-dihydro-5,6-dimethyl-1,4-dithiin

✍ Scribed by A. D. Brewer; A. A. Znotins

Book ID: 112131453
Publisher: Journal of Heterocyclic Chemistry
Year: 1996
Tongue: English
Weight: 157 KB
Volume: 33
Category: Article
ISSN: 0022-152X
DOI: 10.1002/jhet.5570330138

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In the electron impact induced fragmentation of 2,3-disubstituted 5,6-dihydro-1,4-oxathiines, the cleavage of the heterocyclic ring proceeds through the retro Diels-Alder type of reaction. The further fragmentation of the resulting radical cation gives rise to substituted carbonyl or thiocarbonyl ca