## Abstract Reaction of adriamycinone with excess ^14^CH~3~Mgl and periodate cleavage of the resulting glycol (5) affords daunomycinone‐14‐^14^C (6). Bromination and hydrolysis of 6 gives adriamycinone‐14‐^14^C (8). Coupling of 6 and the 14‐0‐p‐anisyldiphenyl‐methyl derivative (9) with 1‐chloro‐3‐N
The synthesis of 14C-acetoin and homoacetoin
✍ Scribed by Joseph L. Rabinowitz
- Publisher
- John Wiley and Sons
- Year
- 1975
- Tongue
- French
- Weight
- 88 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0022-2135
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The synthesis of lanosterol [la] and desmosterol [Ira] Iabeled with 14C in the 25 position by a Wittig reaction between triphenyl-214C isopropylidene-phosphorane [IVb] and the corresponding aldehydes are described. The specijic activities obtained are, respectively, 0.539 mClmM and 0.752 mClmM and t
## Abstract The syntheses of 1‐m‐trifluoromethylphenyl‐2‐N‐ethylaminopropane (I; Ponderax®) and 1‐m‐trifluoromethylphenyl‐2‐N‐β‐benzoyloxyethylaminopropane (II; S780) labelled with carbon‐14 at the benzylic position have been accomplished in seven stages starting from Ba^14^CO~3~. The overall radio
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