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The synthesis and crystal structure of [Cr(acacen)py2] [ZnCl3py]

✍ Scribed by Paul J. Toscano; Peter T. DiMauro; Silvano Geremia; Lucio Randaccio; Ennio Zangrando


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
536 KB
Volume
217
Category
Article
ISSN
0020-1693

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The ligand properties of 2-(phenacylthio)pyridine towards gold(I) and silver(I) have been investigated. From the reactions of the ligand with acetone solutions of [M(PPh 3 )(acetone)]ClO 4 (M = Ag, Au) under various experimental conditions, complexes [(AuPPh 3 ) n {py{SCH 2 C(O)Ph}-2}](ClO 4 ) n , a