The crystal structures of polymeric octahedral bis-pyridine metal dihalide (Py2MX2) complexes
β Scribed by A.A. McConnell; R.H. Nuttall
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 212 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0022-2860
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The ligand properties of 2-(phenacylthio)pyridine towards gold(I) and silver(I) have been investigated. From the reactions of the ligand with acetone solutions of [M(PPh 3 )(acetone)]ClO 4 (M = Ag, Au) under various experimental conditions, complexes [(AuPPh 3 ) n {py{SCH 2 C(O)Ph}-2}](ClO 4 ) n , a
Neutral manganese and nickel complexes of the empirical formulae Mn(H 2 daps)(H 2 O) 0.5 and Ni(H 2 daps) (H 2 O) 1.5 (CH 3 CN) have been prepared by electrochemical syntheses. The structures of the complexes formed from solvents with different donor ability were investigated. Recrystallisation of M