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Synthesis and Structural Characterization of Gold(I) and Silver(I) Complexes of the Multidonor Ligand 2-(Phenacylthio)pyridine − Crystal Structures of [(AuPPh3){py{SCH2C(O)Ph}-2}](ClO4) and [(AgPPh3)(OClO3){py{SCH2C(O)Ph}-2}]

✍ Scribed by José Vicente; Maria-Teresa Chicote; Sonia Huertas; M. Carmen Ramírez de Arellano; Peter G. Jones

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
487 KB
Volume
1998
Category
Article
ISSN
1434-1948

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✦ Synopsis

The ligand properties of 2-(phenacylthio)pyridine towards gold(I) and silver(I) have been investigated. From the reactions of the ligand with acetone solutions of [M(PPh 3 )(acetone)]ClO 4 (M = Ag, Au) under various experimental conditions, complexes [(AuPPh 3 ) n {py{SCH 2 C(O)Ph}-2}](ClO 4 ) n , and [(AgPPh 3 ) n (OClO 3 ) n {py{SCH 2 C(O)Ph}-2}] (n = 1Ϫ3) have been obtained. The crystal structures of the complexes

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