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The synthesis and crystal structure analysis of novel macrocyclic peroxides

โœ Scribed by Kevin J McCullough; Toyonari Ito; Takahiro Tokuyasu; Araki Masuyama; Masatomo Nojima

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
104 KB
Volume
42
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Bis(syn-collidine)iodine(I) hexafluorophosphate-mediated cyclization of unsaturated hydroperoxides afforded the corresponding 11-to 16-membered macrocyclic peroxides having three peroxide units located within one ring. The crystal structures of three novel macrocyclic triperoxides were unambiguously determined by X-ray analysis.

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