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Synthesis, crystal structures and properties of two novel macrocyclic nickel(II) and copper(II) complexes

✍ Scribed by Yan-Hui Su; Jie Liu; Jia Li; Xue-Zhi Si


Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
594 KB
Volume
837
Category
Article
ISSN
0022-2860

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Three new metal complexes, Cu(4-Hcba) 2 (4-cba) 2 (Py) 2 (4-HcbaZ4-cyanobenzoic acid) 1 and M[H(4-cba) 2 ] 2 (Py) 2 (MZNi 2, Co 3), have been prepared by the treatment of 4-Hcba with the respective metal nitrate M(NO 3 ) 2 (MZCu, Ni, Co) in the presence of pyridine (Py). Single-crystal X-ray diffrac