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Synthesis and crystal structure of a dinitrogen ruthenium(II) macrocyclic tertiary amine complex

✍ Scribed by Wing-Hong Chiu; Chi-Ming Che; Thomas C.W. Mak


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
213 KB
Volume
15
Category
Article
ISSN
0277-5387

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A dinuclear manganese macrocyclic complex with functional pendant arms, [Mn 2 (II)HL 2 ](ClO 4 ), has been prepared by the cyclocondensation of sodium 2,6-diformyl-4-methylphenolate with N,N-bis(2-aminoethyl)-N-(2-hydroxybenzyl)amine and subsequent transmetallation of Mn(II)(ClO 4 ) 2 . In the molec