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Synthesis and crystal structures of novel macrocyclic compounds and their inclusion phenomenon

โœ Scribed by Hirohiko Houjou; Kazuhisa Hiratani; Yoshinobu Nagawa; Midori Goto


Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
230 KB
Volume
40
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Four kinds of macrocyclic polyethers containing isobutenyl group and aromatic rings were synthesized. X-ray analyses of crystal structure revealed significant differences in conformation among the compounds studied, in spite of their similarity in chemical formula. One compound was found to capture a benzene molecule in crystalline phase, while the others did not.


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Bis(syn-collidine)iodine(I) hexafluorophosphate-mediated cyclization of unsaturated hydroperoxides afforded the corresponding 11-to 16-membered macrocyclic peroxides having three peroxide units located within one ring. The crystal structures of three novel macrocyclic triperoxides were unambiguously