Synthesis and crystal structures of novel macrocyclic compounds and their inclusion phenomenon
โ Scribed by Hirohiko Houjou; Kazuhisa Hiratani; Yoshinobu Nagawa; Midori Goto
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 230 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Four kinds of macrocyclic polyethers containing isobutenyl group and aromatic rings were synthesized. X-ray analyses of crystal structure revealed significant differences in conformation among the compounds studied, in spite of their similarity in chemical formula. One compound was found to capture a benzene molecule in crystalline phase, while the others did not.
๐ SIMILAR VOLUMES
Bis(syn-collidine)iodine(I) hexafluorophosphate-mediated cyclization of unsaturated hydroperoxides afforded the corresponding 11-to 16-membered macrocyclic peroxides having three peroxide units located within one ring. The crystal structures of three novel macrocyclic triperoxides were unambiguously