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Novel Podands and Macrocycles with Diacetal (Tetraoxadecalin) Cores: Synthesis, Structure, Stereochemistry and Cation Inclusion

✍ Scribed by Sarah Abramson; Eli Ashkenazi; Klaus Frische; Israel Goldberg; Larisa Golender; Moshe Greenwald; N. Gabriel Lemcoff; Ravit Madar; Sarah Weinman; Benzion Fuchs


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
291 KB
Volume
9
Category
Article
ISSN
0947-6539

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The reactions of diacids with the bicyclophosphane 1 lead to podands 3a-f in which two dioxazaphosphocane moieties are linked by a more or less rigid spacer owing to the starting diacid. Macrocycles 4a-b are. obtained by cyclixation of podands 3a-b by way of Michaelis-Becker reaction. The formation