The structure of fumitremorgin A
โ Scribed by Nancy Eickman; Jon Clardy; R.J. Cole; Jerry W. Kirksey
- Book ID
- 104213989
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 142 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
noeiwd in UIC for pblioation 17 Rbnmry 1975) Recently there has been considerable interest in tremor-producing metabolites from fungi.' We1 and others2 have been interested in a class of tremorgens that formally constitute a combination of tryptophan, proline, mevalonate derived units and oxygen. Yamazaki2 has reported on the isolation and structure (without stereochemistry) of fumitremorgin B2 (I.) from Aspergillus fumigatus Fres and we have reported the isolation and structure of the novel peroxide verruculogenl (2) from Penicillium verruculosum. Yamazaki2 reported the
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The reaction of (L)-tryptophan methyl ester with butynone yields a key cis-l,3-disubstituted-tetrahydro-8-carboline (3), simple