1 H and 13 C NMR spectral data for phytochelatin, NH 3 C --Glu-Cys 2 -Gly-COO , were assigned by a combination of one-( 1 H, 13 C) and two-dimensional (DQF-COSY, CH-COSY, HMBC) NMR experiments.
The structure and first 1H NMR spectral assignment of piperazine-C60 adducts
✍ Scribed by Craig P Butts; Remco W.A Havenith; Mikael Jazdzyk; Thomas Drewello; Sotirios Kotsiris
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- French
- Weight
- 94 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
The 1 H NMR spectrum of the piperazine-C 60 monoadduct has been assigned for the first time almost 10 years after it was synthesised. The preparation and characterisation of the first (C2-substituted piperazine)-C 60 monoadduct are also described, revealing the C2-substituent as occupying an exo position on the addend.
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