𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The strong influence of the solvent on the spin distribution in 1,2-benzosemiquinones

✍ Scribed by Jens Arne Pedersen; Jens Spanget-Larsen

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
428 KB
Volume
35
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

A recently developed procedure to treat solvent effects of ring proton byperfiie constutts of semiquinones is npplied to I$-benzosemiquinone and its two mono-methyl derivatives. The results imply that the spin distribution is largely determined by the influence of the solvent. This explains the failure of traditional calc&tions :o describe the ESR spectm of these radicals.

📜 SIMILAR VOLUMES

Influence of the water content of the so
Influence of the water content of the solvent on the product distribution in the electrohydrodimerization of 2-cyclohexenones
✍ Paul Tissot; Jean-Paul Surbeck; Fazil O. Gülaçar; Paul Margaretha 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 German ⚖ 274 KB

## Abstract The product distribution of compounds **2**, **3** and **4** formed in the electrohydrodimerization (EHD) of **1** was determined as function of the water content of the solvent (CH~3~CN). The presence of water favours the formation of the glycols **4** and reduces the relative amounts