A recently developed procedure to treat solvent effects of ring proton byperfiie constutts of semiquinones is npplied to I$-benzosemiquinone and its two mono-methyl derivatives. The results imply that the spin distribution is largely determined by the influence of the solvent. This explains the fail
β¦ LIBER β¦
On the spin distribution in the monoprotonated 1,4-Benzosemiquinone radical
β Scribed by Jens Spanget-Larsen
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 299 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0009-2614
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## Abstract Radical anions of benzo[2.2]paracyclophane (V) and its 1,2,12,12,14,15,17,18βoctadeuterio derivative (Vβd~8~) in three ethereal solvents (DME, THF and MTHF) and in the temperature range of β90 to β50Β° have been studied by ESR. and ENDOR. spectroscopy. The resulting hyperfine data provid