The influence of β-substitution on spin distribution in iron(III) tetraphenylporphyrins
✍ Scribed by Jacek Wojaczyński; Witold Hrycyk; Lechosław Latos-Grażyński; Ludmila Szterenberg; Krystyna Rachlewicz; Ewa Pacholska
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 75 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0162-0134
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
A recently developed procedure to treat solvent effects of ring proton byperfiie constutts of semiquinones is npplied to I$-benzosemiquinone and its two mono-methyl derivatives. The results imply that the spin distribution is largely determined by the influence of the solvent. This explains the fail
The role of alkyl substitution on the electronic structure of cyclohexane radical cation was investigated with low-temperature matrix ESR and semiempirical MO calculations. It was found that the unpaired electron, which is originally delocalized throughout the cyclohexane ring, tends to be confined