Influence of N-Substitution on the Oxidation of 2-Pyridylmethylamines with Bis(trimethylsilyl)amides of Iron(III) – Synthesis of Heteroleptic Iron(II) 2-Pyridylmethylamides
✍ Scribed by Astrid Malassa; Benjamin Schulze; Brigitte Stein-Schaller; Helmar Görls; Birgit Weber; Matthias Westerhausen
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 694 KB
- Volume
- 2011
- Category
- Article
- ISSN
- 1434-1948
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## Abstract The synthesis and crystal structures of three nonheme diiron(III) complexes with a tridentate N,N,O Schiff‐baseligand, 2‐({[2‐(dimethylamino)ethyl]imino}methyl)phenol (HL), are reported. Complexes [Fe~2~OL~2~(NCO)~2~] (1a) and [Fe~2~OL~2~(SAL)~2~]·H~2~O [SAL = __o__‐(CHO)C~6~H~4~O^–^] (